Strategy for Improved Photoconversion Efficiency in Thin Photoelectrode Films by Controlling π-Spacer Dihedral Angle

Citation data:

The Journal of Physical Chemistry C, ISSN: 1932-7447, Vol: 120, Issue: 43, Page: 24655-24666

Publication Year:
2016
Captures 6
Readers 6
Citations 7
Citation Indexes 7
Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/20627
DOI:
10.1021/acs.jpcc.6b08262
Author(s):
Roh, Deok-Ho; Kim, Kwang Min; Nam, Jung Seung; Kim, Un-Young; Kim, Byung-Man; Kim, Jeong-Soo; Kwon, Tae-Hyuk
Publisher(s):
American Chemical Society (ACS); AMER CHEMICAL SOC
Tags:
Materials Science; Energy; Chemistry
article description
Benzo[c][1,2,5]thiadiazole (BT) has been used in dye-sensitized solar cells (DSCs) for its light-harvesting abilities. However, as a strongly electron deficient unit, BT causes rapid back electron transfer (BET), which in turn lowers the photoconversion efficiency (PCE) of devices. Herein, we report a powerful strategy for retarding BET by controlling both the photoelectrode thickness and π-spacer dihedral angle. To achieve this, we introduced planar (BT-T) or twisted π-spacers (BT-P, BT-MP, and BT-HT) between BT units and anchoring groups and used different photoelectrode thicknesses between 1.8 and 10 μm. Computational and experimental results show that twisted π-spacers were more efficient at retarding BET than the planar π-spacer. However, BET was found to be less important than expected, and light harvesting efficiency (LHE) played a critical role as the thickness of the photoelectrode decreased because charge collection efficiency was enhanced. The planar dye BT-T obtained the highest LHE, this value remained unusually high even in 1.8 μm photoelectrodes. As a result, BT-T gave a PCE of 6.5% (J= 13.56 mA/cm, V= 0.67 V, and FF = 0.72) in thin 1.8 μm photoelectrodes with 3.5 μm scattering layers, which represented a roughly 40% enhancement compared to the PCE in 10 μm photoelectrodes (4.76%). Overall, these results provide a novel approach to achieving ultrathin and highly efficient flexible DSCs. (Chemical Equation Presented).