Macroporous Inverse Opal-like MoC with Incorporated Mo Vacancies for Significantly Enhanced Hydrogen Evolution.

Citation data:

ACS nano, ISSN: 1936-086X, Vol: 11, Issue: 7, Page: 7527-7533

Publication Year:
2017
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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/22620
PMID:
28692795
DOI:
10.1021/acsnano.7b04205
Author(s):
Li, Feng; Zhao, Xianglong; Mahmood, Javeed; Okyay, Mahmut Sait; Jung, Sun-Min; Ahmad, Ishfaq; Kim, Seok-Jin; Han, Gao-Feng; Park, Noejung; Baek, Jong-Beom
Publisher(s):
American Chemical Society (ACS); AMER CHEMICAL SOC
Tags:
Materials Science; Engineering; Physics and Astronomy; binding energy; hydrogen evolution; inverse opal; Mo vacancies; molybdenum carbide
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article description
The hydrogen evolution reaction (HER) is one of the most important pathways for producing pure and clean hydrogen. Although platinum (Pt) is the most efficient HER electrocatalyst, its practical application is significantly hindered by high-cost and scarcity. In this work, an MoC with incorporated Mo vacancies and macroporous inverse opal-like (IOL) structure (MoC-IOL) was synthesized and studied as a low-cost efficient HER electrocatalyst. The macroporous IOL structure was controllably fabricated using a facile-hard template strategy. As a result of the combined benefits of the Mo vacancies and structural advantages, including appropriate hydrogen binding energy, large exposed surface, robust IOL structure and fast mass/charge transport, the synthesized MoC-IOL exhibited significantly enhanced HER electrocatalytic performance with good stability, with performance comparable or superior to Pt wire in both acidic and alkaline solutions.