Phytic Acid Doped Polyaniline Nanofibers for Enhanced Aqueous Copper(II) Adsorption Capability

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ACS Sustainable Chemistry & Engineering, ISSN: 2168-0485, Vol: 5, Issue: 8, Page: 6654-6664

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Hyeong Jin Kim; Sungjin Im; Jong Chan Kim; Won G. Hong; Koo Shin; Hu Young Jeong; Young Joon Hong
American Chemical Society (ACS); AMER CHEMICAL SOC
Chemistry; Environmental Science; Chemical Engineering; Energy; Aqueous metal adsorption; Cu2+ ion adsorption; Doping; Phytic acid; Polyaniline; Polymeric nanofiber; Water purification
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This study demonstrates the enhanced Cuadsorption capability of polyaniline nanofibers (PAni NFs) by doping of phytic acid. The PAni NFs were synthesized by radical polymerization process using acidic solutions of hydrochloric and phytic acid, yielding chlorinated (Cl-) and phytic acid-doped (Ph-) PAni NFs. The Ph-PAni NFs showed remarkably higher Cu-adsorption efficiency than Cl-PAni NFs, presumably owing to high capacity and/or high ionic affinity of the doped phytic acid in Ph-PAni NFs. The pH-dependent adsorption capability exhibited increasing Cuadsorption trend as increasing aqueous pH because of spontaneous deprotonation of the doped phytic acid in a basic environment. Furthermore, Ph-PAni NFs showed stable, high Cuadsorption capability, irrespective of Coconcentration in the bimetallic Cu and Co aqueous solution. Surface morphologies of PAni NFs were investigated using electron microscopy, and molecular structures were identified using X-ray photoemission and Fourier transform infrared spectroscopies. The ability of PAni NFs to capture aqueous Cuis discussed in terms of surface functional groups doped to NFs. Surface modification and/or doping to enhance the adsorption capability of Cu(II) introduced in this study will provide a great venue for expanding the use of many other polymeric nanostructures for reclamation in metal mining as well as the conventional environmental applications such as water purification.