Selective Hydrogen Isotope Separation via Breathing Transition in MIL-53(Al).

Citation data:

Journal of the American Chemical Society, ISSN: 1520-5126, Vol: 139, Issue: 49, Page: 17743-17746

Publication Year:
Captures 14
Readers 14
Mentions 1
News Mentions 1
Social Media 1
Tweets 1
Repository URL:
Kim, Jin Yeong; Zhang, Linda; Balderas-Xicohténcatl, Rafael; Park, Jaewoo; Hirscher, M; Moon, Hoi Ri; Oh, Hyunchul
American Chemical Society (ACS); AMER CHEMICAL SOC
Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology
Most Recent Tweet View All Tweets
Most Recent News Mention
article description
Breathing of MIL-53(Al), a flexible metal-organic framework (MOF), leads to dynamic changes as narrow pore (np) transitions to large pore (lp). During the flexible and reversible transition, the pore apertures are continuously adjusted, thus providing the tremendous opportunity to separate mixtures of similar-sized and similar-shaped molecules that require precise pore tuning. Herein, for the first time, we report a strategy for effectively separating hydrogen isotopes through the dynamic pore change during the breathing of MIL-53(Al), a representative of flexible MOFs. The experiment shows that the selectivity for D over H is strongly related to the state of the pore structure of MIL-53(Al). The highest selectivity (S = 13.6 at 40 K) was obtained by optimizing the exposure temperature, pressure, and time to systematically tune the pore state of MIL-53(Al).