CRASY: correlated rotational alignment spectroscopy reveals atomic scrambling in ionic states of butadiene.

Citation data:

The journal of physical chemistry. A, ISSN: 1520-5215, Vol: 119, Issue: 8, Page: 1309-14

Publication Year:
2015
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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/11063
PMID:
25636002
DOI:
10.1021/jp511579z
Author(s):
Schröter, Christian; Choi, Chang Min; Schultz, Thomas
Publisher(s):
American Chemical Society (ACS); AMER CHEMICAL SOC
Tags:
Chemistry; Ionic state; Isotopologues; Rotational alignment
article description
We use correlated rotational alignment spectroscopy to reveal atomic scrambling in transient ionic states of butadiene. Investigating a natural sample, we assign signals of two trans-1,3-butadiene isotopologues that contain a single (13)C isotope and quantify the fragment abundance for the (13)CH3 loss channel for each isotopologue.