CRASY: correlated rotational alignment spectroscopy reveals atomic scrambling in ionic states of butadiene.
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The journal of physical chemistry. A, ISSN: 1520-5215, Vol: 119, Issue: 8, Page: 1309-14
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- Chemistry; Ionic state; Isotopologues; Rotational alignment
We use correlated rotational alignment spectroscopy to reveal atomic scrambling in transient ionic states of butadiene. Investigating a natural sample, we assign signals of two trans-1,3-butadiene isotopologues that contain a single (13)C isotope and quantify the fragment abundance for the (13)CH3 loss channel for each isotopologue.