Thermal conversion of a tailored metal-organic framework into lithium silicate with an unusual morphology for efficient CO₂ capture.

Citation data:

Dalton transactions (Cambridge, England : 2003), ISSN: 1477-9234, Vol: 44, Issue: 34, Page: 15130-4

Publication Year:
2015
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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/18005
PMID:
25960313
DOI:
10.1039/c5dt00690b
Author(s):
Lee, Jae Hwa, Moon, Byoungnam, Kim, Tae Kyung, Jeoung, Sungeun, Moon, Hoi Ri
Publisher(s):
Royal Society of Chemistry (RSC), ROYAL SOC CHEMISTRY, The Royal Society of Chemistry
Tags:
Chemistry, HIGH-TEMPERATURE, CARBON-DIOXIDE, POROUS CARBON, ABSORPTION, LI4SIO4, OXIDES, CHEMISORPTION, SORBENTS, OPTION, ROUTE
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article description
The conversion reaction of metal-organic frameworks (MOFs) was adopted as a synthetic method to produce an advanced CO2 absorbent. A Li- and Si-containing MOF is a good precursor for lithium orthosilicate (Li4SiO4); the resulting solid has an unusual coral-like morphology, which provides an enhanced CO2-sorption performance (high uptake and fast absorption).

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