Thermal conversion of a tailored metal-organic framework into lithium silicate with an unusual morphology for efficient CO₂ capture.
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Dalton transactions (Cambridge, England : 2003), ISSN: 1477-9234, Vol: 44, Issue: 34, Page: 15130-4
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- Chemistry; HIGH-TEMPERATURE; CARBON-DIOXIDE; POROUS CARBON; ABSORPTION; LI4SIO4; OXIDES; CHEMISORPTION; SORBENTS; OPTION; ROUTE
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The conversion reaction of metal-organic frameworks (MOFs) was adopted as a synthetic method to produce an advanced CO2 absorbent. A Li- and Si-containing MOF is a good precursor for lithium orthosilicate (Li4SiO4); the resulting solid has an unusual coral-like morphology, which provides an enhanced CO2-sorption performance (high uptake and fast absorption).