Polypyrrole-assisted oxygen electrocatalysis on perovskite oxides

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Energy and Environmental Science, ISSN: 1754-5706, Vol: 10, Issue: 2, Page: 523-527

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Lee, Dong-Gyu; Kim, Su Hwan; Joo, Se Hun; Ji, Ho-Il; Tavassol, Hadi; Jeon, Yuju; Choi, Suhyuk; Lee, Myeing-Hee; Kim, Chanseok; Kwak, Sang Kyu; Kim, Guntae; Song, Hyun-Kon Show More Hide
Royal Society of Chemistry (RSC); The Royal Society of Chemistry; ROYAL SOC CHEMISTRY
Environmental Science; Energy
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Nitrogen-containing electrocatalysts, such as metal-nitrogen-carbon (M-N-C) composites and nitrogen-doped carbons, are known to exhibit high activities for an oxygen reduction reaction (ORR). Moreover, even if the mechanism by which nitrogen improves the activities is not completely understood, a strong electronic interaction between nitrogen and active sites has been found in these composites. Herein, we demonstrate a case in which nitrogen improves the electroactivity, but in the absence of a strong interaction with other components. The overpotentials of the ORR and oxygen evolution reaction (OER) on perovskite oxide catalysts were significantly reduced simply by mixing the catalyst particles with polypyrrole/carbon composites (pPy/C). Any strong interactions between pPy (a nitrogen-containing compound) and active sites of the catalysts are not confirmed. A scenario based on the sequential task allocation between pPy and oxide catalysts for the ORR was proposed: (1) molecular oxygen is incorporated into pPy as a form of superoxide (pPyO), (2) the superoxide is transferred to the active sites of perovskite catalysts, and (3) the superoxide is completely reduced along the 4e ORR process.