Nonaqueous arylated quinone catholytes for lithium–organic flow batteries

Citation data:

Journal of Materials Chemistry A, ISSN: 2050-7488, Vol: 6, Issue: 30, Page: 14761-14768

Publication Year:
2018

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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/24671
DOI:
10.1039/c8ta04720k
Author(s):
Shin, Dong-Seon; Park, Minjoon; Ryu, Jaechan; Hwang, Inchan; Seo, Jeong Kon; Seo, Kwanyong; Cho, Jaephil; Hong, Sung You
Publisher(s):
Royal Society of Chemistry (RSC); ROYAL SOC CHEMISTRY
Tags:
Chemistry; Energy; Materials Science
article description
Chemically modified organic redox couples have the advantages of tunable redox properties, high solubility, environmental benignity, and cost effectiveness. Inspired by nature, a series of quinone derivatives bearing electron-donating methoxy or electron-withdrawing trifluoromethyl groups are synthesized in moderate to high yields by Pd-catalyzed Suzuki cross-coupling reactions. This study utilizes the synthetic quinones as redox-active organic molecules for nonaqueous lithium-organic flow batteries. The aryl moiety incorporated quinone scaffolds show enhanced electrochemical stability and rate capability. The nonaqueous catholyte, 2-phenyl-1,4-naphthoquinone, reaches a cell voltage of ∼2.6 V and a specific capacity of 196 mA h g, while the discharge capacity is retained at ∼92% for 150 cycles. Moreover, the tubular lithium-organic flow battery system features stable cycle performance under a continuous circulation without clogging-associated intermittency flow.