A highly hydrophobic fluorographene-based system as an interlayer for electron transport in organic–inorganic perovskite solar cells

Citation data:

Journal of Materials Chemistry A, ISSN: 2050-7488, Vol: 6, Issue: 38, Page: 18635-18640

Publication Year:
2018
Captures 14
Readers 14
Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/24934
DOI:
10.1039/c8ta05811c
Author(s):
Javaid, Saqid; Myung, Chang Woo; Pourasad, S.; Rakshit, Bipul; Kim, Kwang S.; Lee, Geunsik
Publisher(s):
Royal Society of Chemistry (RSC); ROYAL SOC CHEMISTRY
Tags:
Chemistry; Energy; Materials Science
article description
Degradation of perovskite halide materials under humid conditions is one of the major hurdles in the commercialization of organic-inorganic perovskite solar cells. Herein, we studied the interface between highly hydrophobic fluorographene (FGr) and cubic methylammonium lead iodide (MAPbI, MA: CH-NH) by employing density functional theory (DFT)-based simulations. We demonstrate that the adsorption of FGr on MAPbIresults in the formation of a stable interface with appreciable binding energy (∼0.4 eV per Pb atom). Thorough assessment of energy-level alignment indicates that the FGr/MAPbIinterface has desirable properties with regard to the electron transfer (hole blockage) process. These results underscore the potential of using FGr as an interlayer for electron transport between a perovskite layer and an electron transfer medium (such as TiO) as well as a moisture blocker for achieving high perovskite stability by perfect waterproofing. The future research study towards the integration of hydrophobic FGr or electronically optimized partially fluorinated graphene-based systems within perovskite halide photovoltaic devices may pave the way for stable and efficient solar cell technologies.