Highly improved photocurrents of dye-sensitized solar cells containing ultrathin 3D inverse opal electrodes sensitized with a dithienothiophene-based organic dye

Citation data:

RSC Adv., ISSN: 2046-2069, Vol: 4, Issue: 77, Page: 40980-40984

Publication Year:
2014
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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/6643
DOI:
10.1039/c4ra06847e
Author(s):
Kwon, Tae-Hyuk, Ha, Su-Jin, Kim, Jeong Soo, Cho, Chang-Yeol, Lee, Jung Woo, Han, Hyun-Gyu, Moon, Jun Hyuk
Publisher(s):
Royal Society of Chemistry (RSC), ROYAL SOC CHEMISTRY, The Royal Society of Chemistry
Tags:
Chemical Engineering, Chemistry, Dye-Sensitized solar cell, Inverse opal, Organic dye, Ultra-thin
article description
Ultrathin but highly efficient dye-sensitized solar cells (DSCs) may be beneficial for making flexible devices and lowering production costs. Here, a uniform, ultrathin inverse opal (IO) electrode sensitized with a dithienothiophene (DTT)-based sensitizer (Carbz-PAHTDTT) was successfully prepared and demonstrated as a high-efficiency DSC electrode. The ultrathin IO was fabricated using a polystyrene opal template subsequently coated with TiOvia a chemical vapor deposition approach. The Carbz-PAHTDTT-sensitized IO film was compared to an IO film sensitized by a conventional N719 dye. The charge collection efficiency of the Carbz-PAHTDTT-sensitized TiOIO electrode was comparable to the N719-sensitized electrode. However, the Carbz-PAHTDTT TiOIO electrode DSCs exhibited remarkably high light-harvesting efficiency due to high adsorption density and visible light absorption features of the Carbz-PAHTDTT-sensitized electrode. The Carbz-PAHTDTT DSCs containing a 3.5 μm thick IO electrode displayed a photocurrent density of 11.23 mA cm, which was 1.5 times higher compared to the N719-sensitized DSCs.

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