Solvent-induced single-crystal to single-crystal transformation of a Zn 4 O-containing doubly interpenetrated metal–organic framework with a pcu net

Citation data:

CrystEngComm, ISSN: 1466-8033, Vol: 17, Issue: 46, Page: 8807-8811

Publication Year:
2015
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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/17952
DOI:
10.1039/c5ce01074h
Author(s):
Lee, Jae Hwa; Kim, Tae Kyung; Suh, a Myunghyun Paik; Moon, Hoi Ri
Publisher(s):
Royal Society of Chemistry (RSC); ROYAL SOC CHEMISTRY; The Royal Society of Chemistry
Tags:
Chemistry; Materials Science; Physics and Astronomy; GAS-SORPTION PROPERTIES; BILAYER OPEN FRAMEWORK; PI-PI-INTERACTIONS; GUEST EXCHANGE; COORDINATION POLYMER; TEMPERATURE; DYNAMICS; REMOVAL; BINDING; SITES
article description
Guest molecules in a metal-organic framework (MOF), [ZnO(CPMA)]·6DMF (DMF = N,N-dimethylformamide), with an interpenetrating pcu net were exchanged with benzene, n-hexane, and methanol in a single-crystal to single-crystal (SC-SC) manner, which involved the sliding motion of the interpenetrating network, as well as the dynamic movements of the molecular components, and was triggered by host-guest interactions.