Solvent-induced single-crystal to single-crystal transformation of a Zn 4 O-containing doubly interpenetrated metal–organic framework with a pcu net
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CrystEngComm, ISSN: 1466-8033, Vol: 17, Issue: 46, Page: 8807-8811
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- Chemistry; Materials Science; Physics and Astronomy; GAS-SORPTION PROPERTIES; BILAYER OPEN FRAMEWORK; PI-PI-INTERACTIONS; GUEST EXCHANGE; COORDINATION POLYMER; TEMPERATURE; DYNAMICS; REMOVAL; BINDING; SITES
Guest molecules in a metal-organic framework (MOF), [ZnO(CPMA)]·6DMF (DMF = N,N-dimethylformamide), with an interpenetrating pcu net were exchanged with benzene, n-hexane, and methanol in a single-crystal to single-crystal (SC-SC) manner, which involved the sliding motion of the interpenetrating network, as well as the dynamic movements of the molecular components, and was triggered by host-guest interactions.