Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

Citation data:

CrystEngComm, ISSN: 1466-8033, Vol: 19, Issue: 27, Page: 3719-3722

Publication Year:
2017
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  • article Summary
    • Repository URL:
    http://scholarworks.unist.ac.kr/handle/201301/22427
    DOI:
    10.1039/c6ce02652d
    Author(s):
    Lee, Jae Hwa; Park, Sungbin; Jeoung, Sungeun; Moon, Hoi Ri
    Publisher(s):
    Royal Society of Chemistry (RSC); The Royal Society of Chemistry; ROYAL SOC CHEMISTRY
    Tags:
    Chemistry; Materials Science; Physics and Astronomy
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    article description
    A 2D interdigitated [Ni(adipate)(spy)(HO)] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.