Metal-Free Multicomponent Reaction for Synthesis of 4,5-Disubstituted 1,2,3-(NH)-Triazoles
Advanced Synthesis and Catalysis, ISSN: 1615-4169, Vol: 360, Issue: 10, Page: 1949-1953
2018
- 28Citations
- 10Captures
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Article Description
A metal-free domino reaction was developed for efficient synthesis of 4,5-disubstituted 1,2,3-(NH)-triazoles by sequentially coupling sulfur salts with aldehydes and sodium azide. In the presence of L-proline, olefinic sulfur salt intermediates rather than epoxides are formed in situ via the coupling of sulfur salts with aldehydes and cyclize with azide ion. This process features mild conditions, high efficiency, commercially available starting materials, and wide substrate scope. (Figure presented.).
Bibliographic Details
Wiley
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