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The Total Synthesis of Heraclemycin B through β-Ketosulfoxide and Aldehyde Annulation

Asian Journal of Organic Chemistry, ISSN: 2193-5807, Vol: 4, Issue: 9, Page: 936-942
2015
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Article Description

Herein we describe a total synthesis of the natural product heraclemycinB. This synthetic approach follows a Diels-Alder strategy to form the anthracenone core followed by a β-ketosulfoxide and aldehyde annulation to form the 4-pyranone Dring. The spectral data for the synthesized product matches that reported in the isolation studies.

Bibliographic Details

Kieran D. Jones; James E. Rixson; Scott G. Stewart; Brian W. Skelton; Kersten M. Gericke

Wiley

Chemistry

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