Reversible metal-free carbon dioxide binding by frustrated lewis pairs
Angewandte Chemie - International Edition, ISSN: 1433-7851, Vol: 48, Issue: 36, Page: 6643-6646
2009
- 669Citations
- 446Captures
- 4Mentions
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Metrics Details
- Citations669
- Citation Indexes663
- 663
- CrossRef654
- Patent Family Citations6
- Patent Families6
- Captures446
- Readers446
- 446
- Mentions4
- References4
- Wikipedia4
Article Description
Hot and bothered? Frustrated Lewis pairs comprising phosphine and borane react to reversibly bind and release CO, offering a rare example of metal-free CO sequestration. The mechanism of formation of these CO derivatives 1 and 2 (see scheme) by almost simultaneous P - C and O - B bond formation was characterized by quantum chemical calculations. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
Bibliographic Details
Wiley
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