Synthesis of two luminescent coordination polymers based on self-assembly of Zn(II) with polycarboxylic acids ligands and heteroaromatic N-donor
Applied Organometallic Chemistry, ISSN: 0268-2605, Vol: 20, Issue: 1, Page: 44-50
2006
- 23Citations
- 6Captures
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Article Description
Using the principles of molecular self-assembly, two novel zinc complexes {[Zn(phth)(bipy)(HO)] [Zn(phth)(bipy)]·HO}n (1) and [Zn(1,2,4-btc)(bipy)(HO)·2HO]n (2) were obtained by hydrothermal reaction of Zn(CHCOO) ·2HO with phthalic acid (phth), 1,2,4-benzenetricarboxylic acid (1,2,4-btc) and 2,2′-bipyridine (bipy) respectively, and characterized by single-crystal X-ray diffraction. The crystal structures reveal that both complexes form one-dimensional chain structures, and the zinc ions are five-coordinated; there are two types of metal environment in the structure of the complex 1. The photophysical properties have been investigated with fluorescence excitation and emission spectra. Copyright © 2005 John Wiley & Sons, Ltd.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=30544446174&origin=inward; http://dx.doi.org/10.1002/aoc.1009; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33748319438&origin=inward; https://onlinelibrary.wiley.com/doi/10.1002/aoc.1009; https://dx.doi.org/10.1002/aoc.1009
Wiley
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