SuFEx-Functionalized Quinones via Ruthenium-Catalyzed C−H Alkenylation: A Potential Building Block for Bioactivity Valorization
Chemistry - An Asian Journal, ISSN: 1861-471X, Vol: 19, Issue: 22, Page: e202400757
2024
- 2Citations
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Article Description
Herein, we describe the Ru-catalyzed C−H alkenylation of 1,4-naphthoquinones (1,4-NQs), resulting in 1,4-naphthoquinoidal/SuFEx hybrids with moderate to good yields. This method provides a novel route for direct access to ethenesulfonyl-fluorinated quinone structures. We conducted mechanistic studies to gain an in-depth understanding of the elementary steps of the reaction. Additionally, we evaluated the prototypes against trypomastigote forms of T. cruzi, leading to the identification of compounds with potent trypanocidal activity.
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