Organic nitrate functional nanoparticles for the glutathione-triggered slow-release of nitric oxide
Journal of Polymer Science, Part A: Polymer Chemistry, ISSN: 1099-0518, Vol: 52, Issue: 15, Page: 2099-2103
2014
- 15Citations
- 20Captures
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Article Description
Nitrate-containing amphiphilic block copolymer chains were self-assembled into micellar nanostructures as a reservoir for the slow-release delivery of nitric oxide (NO). Poly(oligo(ethylene glycol) methyl ether methacrylate)-block- poly(vinyl benzyl chloride-co-styrene) was prepared by reversible addition fragmentation chain transfer (RAFT) polymerization. Pendant chloro- groups in the polymer backbone were reacted with silver nitrate (AgNO) to introduce nitrate functionality. The nitrate-containing micelles proved to be stable in water, with no detectableNOrelease. The release ofNOwas then triggered by exposure to glutathione, and it was found that 36 and 99% of NO was released at 37 and 60° C, respectively, after 21 h. © 2014 Wiley Periodicals, Inc.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84903210468&origin=inward; http://dx.doi.org/10.1002/pola.27221; https://onlinelibrary.wiley.com/doi/10.1002/pola.27221; http://onlinelibrary.wiley.com/wol1/doi/10.1002/pola.27221/fullpdf; https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fpola.27221; https://dx.doi.org/10.1002/pola.27221
Wiley
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