Rotationally Resolved REMPI Spectra of CaH in a Molecular Beam
Journal of Molecular Spectroscopy, ISSN: 0022-2852, Vol: 212, Issue: 1, Page: 17-21
2002
- 11Citations
- 8Captures
- 1Mentions
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Article Description
Rotationally resolved spectra of the CaH radical using a supersonic molecular beam are reported. Thus, high energy resolution of the (1+1′) REMPI spectra corresponding to the A ← X and B ← X electronic transitions were measured which allowed for the first time a clear and precise analysis of the low rotational part ( J ≤7) of the CaH spectrum. A comparison with previous studies revealed that the commonly accepted energy separation between the two band heads of B − X ( v ′=1, v ′=0) of 10 cm −1 is not correct. A value of ca. 1.6 cm −1 was found to be more realistic. On the other hand, the present study confirmed that the perturbation appears only for v ′=1, N ′>3 of the B state.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0022285202985310; http://dx.doi.org/10.1006/jmsp.2002.8531; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0036016589&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0022285202985310; https://dx.doi.org/10.1006/jmsp.2002.8531
Elsevier BV
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