Relativistic string-based electron correlation methods
Challenges and Advances in Computational Chemistry and Physics, ISSN: 2542-4483, Vol: 10, Page: 407-449
2010
- 6Citations
- 19Captures
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Book Chapter Description
Highly-accurate relativistic electronic-structure studies on heavy elements require general and efficient many-body methods. In order to achieve spectroscopic accuracy, the description of in particular dynamic electron correlation is of crucial importance. Modern wavefunction-based electron correlation approaches of high efficiency are typically based on a string representation of many-particle quantities. The focus in this chapter lies on the introduction to a suite of new relativistic electronic-structure methods which treat electron correlation and relativistic effects on the same footing and to a number of concepts of importance for relativistic many-body methods. Several applications to small heavy-element systems are discussed where the presented methods are put to critical tests in direct comparison with other modern approaches of relativistic electronic-structure theory.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80051678444&origin=inward; http://dx.doi.org/10.1007/978-1-4020-9975-5_10; http://link.springer.com/10.1007/978-1-4020-9975-5_10; https://dx.doi.org/10.1007/978-1-4020-9975-5_10; https://link.springer.com/chapter/10.1007/978-1-4020-9975-5_10; http://www.springerlink.com/index/10.1007/978-1-4020-9975-5_10; http://www.springerlink.com/index/pdf/10.1007/978-1-4020-9975-5_10
Springer Science and Business Media LLC
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