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Kinetic studies of elementary chemical steps with relevance in combustion and environmental chemistry

Green Energy and Technology, ISSN: 1865-3537, Vol: 0, Issue: 9781447153061, Page: 607-628
2013
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Book Chapter Description

Elementary chemical reaction steps, relevant to combustion and environmental chemistry, involve in many cases the reaction between a radical species and a closed-shell molecule. Rate constants and product branching ratios of such elementary reactions are important input parameter in complex models, describing combustion processes or the chemistry of the atmosphere. Different experimental setups, widely used to study such reactions, are described in this chapter. The main difference consists in the way radicals are generated (either pulsed or continuous) and the way the time resolution is obtained. The coupling of these different experimental setups with commonly used detection methods is also described.

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