From crystal to micelle: A new approach to the micellar structure
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, ISSN: 0923-0750, Vol: 7, Issue: 4, Page: 391-400
1989
- 49Citations
- 10Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Review Description
The structure of sodium and rubidium deoxycholate micellar aggregates in aqueous solutions was found to be helical and to be stabilized mainly by polar interactions. Astonishingly, the lateral surface of the helix is covered by nonpolar groups and the interior part is filled with cations surrounded by water molecules, as in the case of an inverted micelle. This helical model was inferred from the crystal structures of sodium and rubidium deoxycholates and proved by spectroscopic and diffractometric experimental data. The strategy of the approach to the determination of the micellar structure and the comparison with another model, previously proposed for the bile salt micelles, are reported. On the basis of some results obtained for sodium tauro- and glyco-deoxycholates, micellar models are suggested which could account for the biological function of these important conjugated bile salts. © 1989 Kluwer Academic Publishers.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0000371116&origin=inward; http://dx.doi.org/10.1007/bf01079774; http://link.springer.com/10.1007/BF01079774; http://link.springer.com/content/pdf/10.1007/BF01079774; http://link.springer.com/content/pdf/10.1007/BF01079774.pdf; http://link.springer.com/article/10.1007/BF01079774/fulltext.html; http://www.springerlink.com/index/pdf/10.1007/BF01079774; http://www.springerlink.com/index/10.1007/BF01079774; https://dx.doi.org/10.1007/bf01079774; https://link.springer.com/article/10.1007/BF01079774
Springer Science and Business Media LLC
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