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Determination of the directions of the transition dipoles in tetrabutylperylene in stretched polymers

Journal of Fluorescence, ISSN: 1053-0509, Vol: 4, Issue: 1, Page: 83-86
1994
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Article Description

The directions of the transition dipole moments of 2,5,8,11,-tetra-butylperylene were determined from angle-resolved fluorescence depolarization experiments on molecules embedded in a stretched anhydrous nitrocellulose matrix. The absorption transition moments lies almost parallel to the elongated axis of the molecule, but the emission transition moment makes an angle of 20° with the axis. The orientational distribution of the molecules in the polymer indicates significant deviations from a circular form. © 1994 Plenum Publishing Corporation.

Bibliographic Details

Marc A. M. J. van Zandvoort; Pavlik M. Lettinga; Cor van der Struijf; Gijs van Ginkel; Yehudi K. Levine

Springer Nature

Biochemistry, Genetics and Molecular Biology; Psychology; Social Sciences; Chemistry

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