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Rate of abstraction of hydrogen atoms from ethane by muonium

Hyperfine Interactions, ISSN: 0304-3834, Vol: 87, Issue: 1, Page: 911-916
1994
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Article Description

Thermal reaction rates for the gas-phase reaction Mu+CH→MuH+CH have been measured by μSR over the temperature range 510-730 K. The usual Arrhenius expression, k=Aexp(-E/RT), fits the data well, giving parameters A=1.0×10 cm molecule s and E=15.35 kcal/mol. The activation energy E is 5.5 kcal/mol higher than for the H atom variant of this reaction, indicating a marked difference in reaction dynamics. Preliminary analysis indicates a still greater difference between Mu and H for the corresponding CH reaction. © 1994 J.C. Baltzer AG, Science PublishersJ.C. Baltzer AG, Science Publishers.

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