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Study of nuclear electric quadrupole splittings in the high-T phase of Bi-system superconductors

Hyperfine Interactions, ISSN: 0304-3843, Vol: 70, Issue: 1-4, Page: 1215-1218
1992
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Fe Mossbauer measurement have been performed in the Fe-doped high-T phase of Bi-system superconductor. Isomer shifts display presence of Fe ions in square and pyramidal coordinations. Regarding the high-T superconductors as primarily ionic crystals and using effective valence and point charge model, we have calculated the electric field gradients for Fe as a replacement for Cu in the high-T phase. Good agreement between theory and experiment is obtained. © 1992 J.C. Baltzer A.G., Scientific Publishing Company.

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