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Comprehensive gas chromatography of high-boiling halogenated compounds

Chromatographia, ISSN: 0009-5893, Vol: 55, Issue: 5-6, Page: 339-344
2002
  • 15
    Citations
  • 0
    Usage
  • 6
    Captures
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    15
    • Citation Indexes
      15
  • Captures
    6

Article Description

Comprehensive gas chromatography is an excellent technique for separating complex mixtures. If, however high-boiling compounds such as polychlorinated biphenyls have to be analysed, proper adjustiment of the temperature of the modulator turns out to be very important in maintaining the performance of the system. It is shown that miniaturisation of the column-to-modulator coupling, adequate selection of the modulating conditions and, for halogenated compound mixtures, the use of a micro electron-capture detector, can solve experimental problems previously encountered with high boilers.

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