In situ time-resolved FTIR investigation on the reaction mechanism of partial oxidation of methane to syngas over supported Rh and Ru catalysts
Chinese Science Bulletin, ISSN: 1001-6538, Vol: 45, Issue: 24, Page: 2236-2240
2000
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Article Description
In situ time-resolved FTIR spectroscopy was used to study the reaction mechanism of partial oxidation of methane (POM) to synthesis gas and the reaction of CH/O/He (2/1/45, molar ratio) gas mixture with adsorbed CO species over Rh/SiO, Ru/γ-AlO and Ru/SiO catalysts at 500-600°C. It was found that CO is the primary product of POM reaction over reduced and working state Rh/SiO catalysts. Direct oxidation of CH is the main pathway of synthesis gas formation over Rh/SiO catalyst. CO is the primary product of POM over Ru/γ-AlO and Ru/SiO catalysts. The dominant reaction pathway for synthesis gas formation over Ru/γ-AlO catalyst is via the reforming reactions of CH with CO and HO. For the POM reaction over Rh/SiO and Ru/γ-AlO catalysts, consecutive oxidation of surface CO species is an important pathway of CO formation.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0034483219&origin=inward; http://dx.doi.org/10.1007/bf02886360; http://link.springer.com/10.1007/BF02886360; http://link.springer.com/content/pdf/10.1007/BF02886360; http://link.springer.com/content/pdf/10.1007/BF02886360.pdf; http://link.springer.com/article/10.1007/BF02886360/fulltext.html; https://dx.doi.org/10.1007/bf02886360; https://link.springer.com/article/10.1007/BF02886360; http://www.springerlink.com/index/10.1007/BF02886360; http://www.springerlink.com/index/pdf/10.1007/BF02886360
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