Distribution Pattern of Organophosphate Esters in Particle-Size Fractions of Urban Topsoils Under Different Land-Use Types and Its Relationship to Organic Carbon Content

In this study, the distribution pattern of organophosphate esters (OPEs) in particle-size fractions of urban topsoils under different land-use types and its relationship to organic carbon content was investigated. Total OPEs concentrations in different particle-size fractions ranged from 17.07 to 221.77 ng/g. The distribution pattern of total OPEs concentrations and individual OPE concentration in different particle-size fractions were irregular and varied with the land-use type. The mass of OPEs is concentrated in small particles, large particles, or evenly distributed in each particle. This distribution pattern mainly depends on the mass distribution of each fraction to the soil. Tri-iso-butyl phosphate, tributyl phosphate, and triphenylphosphine oxide have a relatively higher concentration in most samples, and the concentration of tripropyl phosphate was the lowest in all samples. The correlations between total OPEs concentrations versus total organic carbon (TOC), black carbon (BC), and other carbon (OC) is weak. Their linear regression correlation coefficients were 0.0495, 0.0823, and 0.0097, respectively. The correlation between individual OPE concentrations versus TOC, BC, and OC also are weak. Except for triethyl phosphate, tris-(2-chloroethyl) phosphate, and tris-(1-chloro-2-propyl) phosphate, the linear regression correlation coefficients of other OPEs are all less than 0.1.