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Enantioselective synthesis of 1-arylethanediols by rhodium-catalyzed transfer hydrogenation of α-tosyloxyarylketones

Monatshefte fur Chemie, ISSN: 0026-9247, Vol: 140, Issue: 1, Page: 73-78
2009
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Catalytic transfer hydrogenation of α-tosyloxyarylketones mediated by a chiral rhodium complex using an azeotropic mixture of formic acid/triethylamine afforded the corresponding 1-arylethanediol monotosylates in excellent yield with high enantioselectivity. © 2008 Springer-Verlag.

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