Ruthenium(III) chloride-catalyzed efficient protocol for ethyl diazoacetate insertion into the N-H bond of secondary amines
Monatshefte fur Chemie, ISSN: 0026-9247, Vol: 139, Issue: 11, Page: 1369-1372
2008
- 7Citations
- 4Captures
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Article Description
Ruthenium(III) chloride (1 mol%) alone can catalyze the insertion of ethyl diazoacetate into N-H bonds of various structurally and electronically diverse secondary cyclic amines under solvent-free conditions to afford the corresponding glycine esters in good yields under ambient conditions. Reactions with various aliphatic primary and aromatic amines examined, however, were unsuccessful. © 2008 Springer-Verlag.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=55349096823&origin=inward; http://dx.doi.org/10.1007/s00706-008-0927-z; http://link.springer.com/10.1007/s00706-008-0927-z; http://link.springer.com/content/pdf/10.1007/s00706-008-0927-z; http://link.springer.com/content/pdf/10.1007/s00706-008-0927-z.pdf; http://link.springer.com/article/10.1007/s00706-008-0927-z/fulltext.html; https://dx.doi.org/10.1007/s00706-008-0927-z; https://link.springer.com/article/10.1007/s00706-008-0927-z; http://www.springerlink.com/index/10.1007/s00706-008-0927-z; http://www.springerlink.com/index/pdf/10.1007/s00706-008-0927-z
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