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ESI-IT-MS and DFT calculation for electron affinities of bimetallic oxovanadium complexes

Monatshefte fur Chemie, ISSN: 0026-9247, Vol: 142, Issue: 11, Page: 1105-1109
2011
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The MS spectra of three bimetallic oxovanadium complexes were obtained using an ion trap. The fragmentation pathways were elucidated. Common features and major differences between ESI-QTOF-MS/MS and ESI-IT-MS spectra were compared. Electron affinities of several radical molecular anions were calculated by DFT and these could be used as an indicator of the ions' stability. © 2011 Springer-Verlag.

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