On the chloride lability in electron-rich second-generation ruthenium benzylidene complexes
Monatshefte fur Chemie, ISSN: 0026-9247, Vol: 146, Issue: 7, Page: 1143-1151
2015
- 15Citations
- 9Captures
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Article Description
A series of electron-rich second-generation cis-dichloro ruthenium aldehyde-chelating benzylidene complexes was prepared, characterized, and tested in typical ring-opening metathesis polymerization (ROMP) experiments. The benzylidene precursors were prepared via etherification of the hydroxyl group and vinylation at position 2 of 2-bromo-5-hydroxy-4-methoxybenzaldehyde. The corresponding ruthenium complexes were obtained from a carbene exchange reaction and were characterized by a cis-dichloro arrangement. A pronounced lability of the chloride ligand trans to the N-heterocyclic carbene ligand in methanol was observed and it was shown that this feature is responsible for a particularly slow ROMP in this solvent. Graphical abstract: [Figure not available: see fulltext.]
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84930865776&origin=inward; http://dx.doi.org/10.1007/s00706-015-1484-x; http://link.springer.com/10.1007/s00706-015-1484-x; http://link.springer.com/content/pdf/10.1007/s00706-015-1484-x; http://link.springer.com/content/pdf/10.1007/s00706-015-1484-x.pdf; http://link.springer.com/article/10.1007/s00706-015-1484-x/fulltext.html; https://dx.doi.org/10.1007/s00706-015-1484-x; https://link.springer.com/article/10.1007/s00706-015-1484-x
Springer Science and Business Media LLC
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