Intramolecular cyclization of isothiocyanyl amino acids/peptide: arrival at unnatural thioxoimidazolidinyl/thioxooxazolidinyl amino acids
Amino Acids, ISSN: 1438-2199, Vol: 54, Issue: 11, Page: 1451-1459
2022
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Article Description
A novel intramolecular cyclization of isothiocyanyl amino acids/peptide is reported to arrive at unnatural thioxoimidazolidinyl (TOI)/thioxooxazolidinyl (TOO) amino acids for the first time. Interestingly, analogous isothiocyanyl amines under a similar reaction condition either follow 5-endo-dig cyclization to offer 5-membered thiourea or acyclic diethylaminyl thiourea derivative instead of 6-membered cyclic thiourea.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85135100914&origin=inward; http://dx.doi.org/10.1007/s00726-022-03186-w; http://www.ncbi.nlm.nih.gov/pubmed/35870054; https://link.springer.com/10.1007/s00726-022-03186-w; https://dx.doi.org/10.1007/s00726-022-03186-w; https://link.springer.com/article/10.1007/s00726-022-03186-w
Springer Science and Business Media LLC
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