PlumX Metrics
Embed PlumX Metrics

Selective oxidation of benzyl alcohol on poly(4-(3-(pyrrol-1-yl)propionamido)-2,2,6,6-tetramethylpiperidin-1-yloxy) electrode

Journal of Solid State Electrochemistry, ISSN: 1432-8488, Vol: 19, Issue: 8, Page: 2291-2297
2015
  • 17
    Citations
  • 0
    Usage
  • 14
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    17
    • Citation Indexes
      17
  • Captures
    14

Article Description

The derivative monomer of pyrrole with the side chain nitroxyl radical, 4-(3-(pyrrol-1-yl)propionamido)-2,2,6,6-tetramethylpiperidin-1-yloxy (PyATEMPO) was synthesized. Its corresponding polymer PPyATEMPO was successfully prepared by cyclic voltammetry on Pt electrode in NaClO/CHCN solution. The PPyATEMPO electrode showed high electrocatalytic activity for oxidation of benzyl alcohol in the presence of the Lewis base 2,6-lutidine. To further investigation, in situ Fourier transform infrared (FTIR) spectroscopy technique was applied to study the possible electrochemical oxidation mechanism of benzyl alcohol on PPyATEMPO electrode. It showed that the benzyl alcohol was selectively oxidized to benzaldehyde in the action of PPyATEMPO film.

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know