The Crystallization, Melting Behaviors and Thermal Stability of Cross-linked Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) by Octavinyloctasilasesquioxane
Chinese Journal of Polymer Science (English Edition), ISSN: 1439-6203, Vol: 36, Issue: 12, Page: 1353-1360
2018
- 14Citations
- 9Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations14
- Citation Indexes14
- 14
- CrossRef2
- Captures9
- Readers9
Article Description
A series of cross-linked poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/octavinyloctasilasesquioxane (PHBV/OVS) composites were obtained by a simple melt reactive processing technique. Dicumyl peroxide (DCP) and OVS were employed as a free radical initiator and a cross-linking agent, respectively. The chemical structure of these produced composites were identified by H/C/Si-nuclear magnetic resonance spectroscopy (H/C/Si-NMR) and Fourier transform infrared spectroscopy (FTIR). The melting behavior, non-isothermal crystallization, spherulite morphology and thermal stability property of PHBV/OVS composites were also investigated. The nucleation behaviors and crystallization rate of PHBV/OVS were significantly enhanced with the formation of cross-linked networks with different side-chains and cross-linking points. The red shift of crystalline peak temperature with addition of a small amount of OVS content evidenced the higher crystalline ability compared with the neat PHBV. However there was a threshold content, beyond which the crystallization rate weakened again. Additionally, the cross-linked structure of PHBV/OVS composites could be adjusted by changing the amount of OVS.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85048588545&origin=inward; http://dx.doi.org/10.1007/s10118-018-2157-0; http://link.springer.com/10.1007/s10118-018-2157-0; http://link.springer.com/content/pdf/10.1007/s10118-018-2157-0.pdf; http://link.springer.com/article/10.1007/s10118-018-2157-0/fulltext.html; http://sciencechina.cn/gw.jsp?action=cited_outline.jsp&type=1&id=6344712&internal_id=6344712&from=elsevier; https://dx.doi.org/10.1007/s10118-018-2157-0; https://link.springer.com/article/10.1007/s10118-018-2157-0
Springer Science and Business Media LLC
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