Methanol to long-chain oxygenates over Mg/Al mixed oxides supported Cu catalysts
Catalysis Letters, ISSN: 1011-372X, Vol: 119, Issue: 1-2, Page: 72-78
2007
- 9Citations
- 13Captures
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Article Description
The synthesis of long-chain oxygenates (C) from methanol is examined at atmospheric pressure and 523-673 K. The Cu-ZnO/d-HT (decomposed hydrotalcite) catalyst shows ca. 10% yield of C at 573 K and a weight hourly space velocity of 0.2 h; whereas, no C is formed over Cu/d-HY, Cu-MgO/AlO, Cu-ZnO/Al O, or a commercial Cu/ZnO methanol synthesis catalyst. The role of the synergistic effect of Cu, ZnO and the basicity of d-HT and the possible reaction intermediates for the C synthesis are discussed. © 2007 Springer Science+Business Media, LLC.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=35349027340&origin=inward; http://dx.doi.org/10.1007/s10562-007-9191-9; http://link.springer.com/10.1007/s10562-007-9191-9; http://link.springer.com/content/pdf/10.1007/s10562-007-9191-9; http://link.springer.com/content/pdf/10.1007/s10562-007-9191-9.pdf; http://link.springer.com/article/10.1007/s10562-007-9191-9/fulltext.html; https://dx.doi.org/10.1007/s10562-007-9191-9; https://link.springer.com/article/10.1007/s10562-007-9191-9; http://www.springerlink.com/index/10.1007/s10562-007-9191-9; http://www.springerlink.com/index/pdf/10.1007/s10562-007-9191-9
Springer Science and Business Media LLC
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