Oxidative dimerization of o-aminophenol by heterogeneous mesoporous material modified with biomimetic salen-type copper(II) Complex
Catalysis Letters, ISSN: 1572-879X, Vol: 143, Issue: 3, Page: 282-288
2013
- 35Citations
- 12Captures
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Article Description
Copper(II) N,N′-bis[4-(N,N-diethylamino)salicylidene]ethylenediamine (CAS) complex, which has the metal-ligand coordination "CuN O" that mimics the galactose enzyme active site, was synthesised and incorporated onto the organo-modified MCM-48. The supported CAS catalyst successfully catalysed the conversion of o-aminophenol to 2-amino-3H-phenoxazon-3-one in the presence of aqueous peroxide as oxidant. The catalytic performance of the CAS supported on organo-modified MCM-48 was found highly affected by the temperature, the type of aqueous peroxide and reaction solvent used. © 2013 Springer Science+Business Media New York.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84878480672&origin=inward; http://dx.doi.org/10.1007/s10562-012-0959-1; http://link.springer.com/10.1007/s10562-012-0959-1; http://link.springer.com/content/pdf/10.1007/s10562-012-0959-1; http://link.springer.com/content/pdf/10.1007/s10562-012-0959-1.pdf; http://link.springer.com/article/10.1007/s10562-012-0959-1/fulltext.html; https://dx.doi.org/10.1007/s10562-012-0959-1; https://link.springer.com/article/10.1007/s10562-012-0959-1
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