Amino-functional imidazolium ionic liquids for CO activation and conversion to form cyclic carbonate
Catalysis Letters, ISSN: 1572-879X, Vol: 144, Issue: 7, Page: 1313-1321
2014
- 78Citations
- 57Captures
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Article Description
A series of amino-functional imidazolium ionic liquids have been prepared and used as catalysts for cycloaddition of CO with epoxide. The reactions generated the cyclic carbonate even at room temperature under atmospheric pressure. Under the optimal reaction conditions, the propylene carbonate was yield to 98.0 % in the presence of [APbim]I, and the ionic liquids could be reused at least nine times without noticeable decrease in activity and selectivity. Besides, the reaction mechanism was proposed. © 2014 Springer Science+Business Media New York.
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Springer Science and Business Media LLC
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