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Suzuki–Miyaura Cross-Coupling in Aqueous Medium Using Recyclable Palladium/Amide-Silica Catalyst

Catalysis Letters, ISSN: 1572-879X, Vol: 146, Issue: 9, Page: 1718-1728
2016
  • 8
    Citations
  • 0
    Usage
  • 11
    Captures
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    Mentions
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    8
    • Citation Indexes
      8
  • Captures
    11

Article Description

Abstract: Silica-immobilized benzamide palladium complex was prepared and characterized. The complex exhibits excellent catalytic activity and stability for Suzuki–Miyaura cross-coupling reaction under mild aqueous reaction condition. Various aryl bromides were coupled with arylboronic acids in i-PrOH/HO, under open air at room temperature, in the presence of 0.22 mol% of the catalyst to afford corresponding cross-coupled products in high yields. Furthermore, the novel heterogeneous catalyst can be conveniently recovered by simple filtration and reused several times without significant loss in activity. Graphical Abstract: [Figure not available: see fulltext.]

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