Behavior of IrCl as a Homogeneous Catalyst on the Oxidation of N-Acetylglucosamine in Acid Medium and Uncatalyzed Reaction in Alkaline Medium with Bromamine-B: Exploration of Kinetic, Mechanistic and Catalytic Chemistry
Catalysis Letters, ISSN: 1572-879X, Vol: 148, Issue: 1, Page: 424-437
2018
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Article Description
Abstract: The experimental rate laws for the oxidation of N-acetylglucosamine with bromamine- B are: − d[BAB]/dt = k [BAB] [GlcNAc] [HClO] [IrCl] [BSA] in acid medium and –d[BAB]/dt = k [BAB] [GlcNAc] [NaOH] in alkaline medium. The IrCl catalyzed reaction is thirteen fold faster than uncatalyzed reaction. Appropriate mechanisms and rate laws were deduced. Graphical Abstract: The reaction of N-acetylglucosamine with Bromamine-B in acid and alkaline medium is [Figure not available: see fulltext.].
Bibliographic Details
Springer Science and Business Media LLC
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