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Special features of 1,3-dipolar cycloaddition of n-methylazomethinylid to nitrobenzazoles

Chemistry of Heterocyclic Compounds, ISSN: 0009-3122, Vol: 47, Issue: 2, Page: 215-221
2011
  • 12
    Citations
  • 0
    Usage
  • 3
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    12
    • Citation Indexes
      12
  • Captures
    3

Article Description

Synthetic approaches to 1,3-dipolar cycloaddition of N-methylazomethinylid to mononitrobenzazole are described. The geometric and electronic structures have been studied by quantum chemical methods (HF/STO-3 G and B3LYP/6-31 G) and the reactivity indexes of compounds have been estimated. It was shown that 1,3-dipolar cycloaddition of N-methylazomethinylid to the dipolarophile has a polar character and proceeds in accordance with the normal (noninversion) electronic distribution. © 2011 Springer Science+Business Media, Inc.

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