Bifunctional electrocatalysts for oxygen reduction/evolution reactions derived from NiCoFe LDH materials
Journal of Applied Electrochemistry, ISSN: 1572-8838, Vol: 48, Issue: 8, Page: 947-957
2018
- 16Citations
- 19Captures
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Article Description
Abstract: Materials obtained from thermal treatment of thermally treated NiCoFe-layered double hydroxides (LDH) with different Ni:Co ratios were evaluated as bifunctional catalysts for Oxygen Reduction Evolution and Evolution Reduction Reactions in alkaline media. The structural properties of synthesized materials were characterized by X-ray diffraction, Fourier-transform infrared, Raman, and X-ray photoelectron spectroscopies, whereas the basicity of each material was evaluated by temperature-programmed desorption of carbon dioxide. The results revealed the presence of inverse spinel structure with different compositions and a NiO phase with different amounts in the sample, while the electrochemical results showed a high activity towards oxygen reactions. The sample with higher amount of NiO and the lowest substitution grade on tetrahedral sites in the spinel-type structure exhibited the best catalytic activity. Graphical Abstract: [Figure not available: see fulltext.].
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85047209427&origin=inward; http://dx.doi.org/10.1007/s10800-018-1210-6; http://link.springer.com/10.1007/s10800-018-1210-6; http://link.springer.com/content/pdf/10.1007/s10800-018-1210-6.pdf; http://link.springer.com/article/10.1007/s10800-018-1210-6/fulltext.html; https://dx.doi.org/10.1007/s10800-018-1210-6; https://link.springer.com/article/10.1007/s10800-018-1210-6
Springer Science and Business Media LLC
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