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Pistacia lentiscus extract as a green inhibitor for copper corrosion in 0.5 M of HSO: electrochemical characterization and theoretical investigations

Journal of Applied Electrochemistry, ISSN: 1572-8838, Vol: 52, Issue: 11, Page: 1629-1646
2022
  • 34
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  • 19
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    34
    • Citation Indexes
      34
  • Captures
    19

Article Description

The current work aims to study the effect of Pistacia lentiscus (Pil) essential oil originating from Chefchaouen city, which is located in northeastern Morocco on the corrosion inhibition of copper in acidic medium HSO 0.5 M. According to gas chromatography coupled with mass spectrometry analysis, the investigated inhibitor is mainly composed of ⍺-pinene (38.35%), limonene (16.98%) and Para-cymene (9.02%). The present study was performed using electrochemical and theoretical investigations. The obtained results indicate that (Pil) acts as an excellent inhibitor for copper in HSO 0.5 M. The inhibition efficiency (IE %) increases with the increase of inhibitor concentration to attain 94% at 2.0 g L. The submerged surface of copper has been identified by SEM/EDS, AFM spectroscopy, and Contact angle measurements (θ). On the other hand, experimental and spectroscopic studies were confirmed using DFT calculations and MD simulations. Graphical abstract: [Figure not available: see fulltext.]

Bibliographic Details

K. Dahmani; M. Ouakki; M. Cherkaoui; M. Galai; A. Ech-chebab; L. Kadiri; Amr Elgendy; R. Ez-Zriouli

Springer Science and Business Media LLC

Chemical Engineering; Chemistry; Materials Science

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