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Synergistic effect of Pd and Sb incorporation on ethanol vapour detection of La doped tin oxide sensor

Journal of Materials Science: Materials in Electronics, ISSN: 1573-482X, Vol: 26, Issue: 12, Page: 9865-9872
2015
  • 15
    Citations
  • 0
    Usage
  • 9
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    15
    • Citation Indexes
      15
  • Captures
    9

Article Description

4 wt% La-doped SnO nanocrystalline powders impregnated with 0.5–1.5 wt% Pd were synthesized by a facile sol–gel method. The powders characterized through XRD, TEM, EDX as well as XPS analyses were used for the fabrication of sensors. 0.5 wt% SbO was incorporated in each case to reduce the resistance of sensors. The gas response studies revealed a large enhancement in low concentration (1–100 ppm) ethanol vapour sensing at comparatively lower operating temperature (300 °C) on 1.0 wt% Pd incorporation. The response observed (~86 %) for 10 ppm vapour was ~16 % greater compared to 4 wt% La-doped SnO with improved response (2 s) and recovery (15 s) times. The high ethanol vapor response at comparatively lower operating temperature of this sensor is attributed to the combinatorial effect of alkalescence of SnO due to La-doping and widening of depleted region by spill-over process of PdO present on SnO surface.

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