Low-temperature fabrication for transparency Mg doping LiLaZrO solid state electrolyte
Journal of Materials Science: Materials in Electronics, ISSN: 1573-482X, Vol: 29, Issue: 2, Page: 1523-1529
2018
- 30Citations
- 37Captures
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Article Description
LiLaZrO (LLZO), which is one of the most promising solid electrolytes, has received great attention toward development of all solid-state lithium ion batteries in recently years due to its high lithium ion conductivity and relative stability against lithium metal at room temperature. However, high sintering-temperature goes against the processing and application of LLZO. Meanwhile, high sintering-temperature will exert great impact on composition and electric property of LLZO for volatilization of LiO. In this study, LLZO is fabricated by doping with Mg to decrease sintering-temperature. Experimental results show that the sintering-temperature of Mg doping LLZO is reduced to 1000 °C, lower about ∼230 °C than that of LLZO. And the sintering-time is shorten to 12 h, reducing about 24 h. In addition, Mg doping LLZO exhibits well stability to lithium metal between 0 and 4.8 V, and exhibits 10–12% transparency to visible light from 500 to 800 nm.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85031901126&origin=inward; http://dx.doi.org/10.1007/s10854-017-8062-4; http://link.springer.com/10.1007/s10854-017-8062-4; http://link.springer.com/content/pdf/10.1007/s10854-017-8062-4.pdf; http://link.springer.com/article/10.1007/s10854-017-8062-4/fulltext.html; https://dx.doi.org/10.1007/s10854-017-8062-4; https://link.springer.com/article/10.1007/s10854-017-8062-4
Springer Nature
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