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Electrochemical performance of FeMn-based metal–organic frameworks as electrode materials for supercapacitors

Journal of Materials Science: Materials in Electronics, ISSN: 1573-482X, Vol: 29, Issue: 23, Page: 19819-19824
2018
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Article Description

We use Fe as dopant in the metal–organic framework (MOF) of [(CH)NH]Mn(HCOO), and four crystals were obtained with hydrothermal method according to the doping ratio: [(CH)NH]Mn(HCOO), [(CH)NH]FeMn(HCOO), [(CH)NH]FeMn(HCOO) and [(CH)NH]FeMn(HCOO). And their electrochemical properties were studied by measuring cyclic voltammetry, galvanostatic charge–discharge and electrochemical impendence spectrum. The results showed that the sample of [(CH)NH]FeMn(HCOO) performed the highest specific electrical capacity of 167.95 F g at a current density of 0.01 A g. This work suggests that a small amount of Fe doping can improve the electrochemical performance of MOFs-based supercapacitors.

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