3D Metal-organic framework based on cadmium complex of pyrazine-2,3,5,6- tetracarboxylic acid
Journal of Chemical Crystallography, ISSN: 1074-1542, Vol: 41, Issue: 8, Page: 1245-1248
2011
- 12Citations
- 7Captures
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Article Description
The 3D metal-organic framework based on cadmium complex of pyrazine-2,3,5,6-tetracarboxylate (pztc), {Cd(pztc) (HO)}, has been synthesized by the reaction of Hpztc and Cd(NO)•4HO under hydrothermal conditions and characterized by elemental analysis, IR, single-crystal X-ray diffraction and fluorescence measurement. This complex belongs to triclinic system, P̄1 space group with a = 5.0080(10) Å, b = 6.6578(13) Å, c = 8.5790(17) Å, α = 89.28(3)°, β = 75.76(3)°, γ = 78.80(3)°. All the donor N and O atoms in pztc coordinate to Cd(II) ions. As decadentate ligand, each pztc links eight Cd(II) atoms, which is a novel coordination mode of pztc. © 2011 Springer Science+Business Media, LLC.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80051795194&origin=inward; http://dx.doi.org/10.1007/s10870-011-0123-6; http://link.springer.com/10.1007/s10870-011-0123-6; http://link.springer.com/content/pdf/10.1007/s10870-011-0123-6; http://link.springer.com/content/pdf/10.1007/s10870-011-0123-6.pdf; http://link.springer.com/article/10.1007/s10870-011-0123-6/fulltext.html; http://www.springerlink.com/index/10.1007/s10870-011-0123-6; http://www.springerlink.com/index/pdf/10.1007/s10870-011-0123-6; https://dx.doi.org/10.1007/s10870-011-0123-6; https://link.springer.com/article/10.1007/s10870-011-0123-6
Springer Science and Business Media LLC
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