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3D Metal-organic framework based on cadmium complex of pyrazine-2,3,5,6- tetracarboxylic acid

Journal of Chemical Crystallography, ISSN: 1074-1542, Vol: 41, Issue: 8, Page: 1245-1248
2011
  • 12
    Citations
  • 0
    Usage
  • 7
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    12
    • Citation Indexes
      12
  • Captures
    7

Article Description

The 3D metal-organic framework based on cadmium complex of pyrazine-2,3,5,6-tetracarboxylate (pztc), {Cd(pztc) (HO)}, has been synthesized by the reaction of Hpztc and Cd(NO)•4HO under hydrothermal conditions and characterized by elemental analysis, IR, single-crystal X-ray diffraction and fluorescence measurement. This complex belongs to triclinic system, P̄1 space group with a = 5.0080(10) Å, b = 6.6578(13) Å, c = 8.5790(17) Å, α = 89.28(3)°, β = 75.76(3)°, γ = 78.80(3)°. All the donor N and O atoms in pztc coordinate to Cd(II) ions. As decadentate ligand, each pztc links eight Cd(II) atoms, which is a novel coordination mode of pztc. © 2011 Springer Science+Business Media, LLC.

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