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Crystal Structure, Dielectric Characteristics and Conduction Mechanism of a New Hybrid Material, Tetra(Phenylpiperazinium) Decachlorotriplumbate(II)

Journal of Cluster Science, ISSN: 1572-8862, Vol: 28, Issue: 6, Page: 3159-3174
2017
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Monocrystalline (CHN)PbCl was obtained via an aqueous solution reaction and characterized by single-crystal X-ray diffraction technique, elemental analyses, IR spectroscopy, UV–Vis spectrum, photoluminescence properties and thermal analysis. Structural characterization reveals that the title compound is built from [PbCl] units sharing Cl2 atom to form 2-D [PbCl] layers, these anions are linked to the organic cations via N–HCl and C–HCl hydrogen bonding. Moreover, dielectric relaxation spectroscopy has also been determined to show different molecular motions. Measurements of AC conductivity as a function of frequency at different temperatures indicated the hopping conduction mechanism.

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