Hydrothermal Syntheses, Crystal Structure and Characterization of Two Alkaline Earth Metal Coordination Polymers with 1-(4-Iodophenyl)-5-methyl-1H-[1,2,3]-triazole-4-carboxylate Ligand
Journal of Inorganic and Organometallic Polymers and Materials, ISSN: 1574-1451, Vol: 24, Issue: 3, Page: 656-663
2014
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- 2Captures
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Article Description
Two new alkaline earth metal coordination polymers [M(ipmtca)(HO)] with M = Ca (1), Sr (2) have been obtained by the reactions of Ca (1) and Sr (2) with 1-(4-iodophenyl)-5-methyl-1H-[1,2,3]-triazole-4-carboxylic acid, respectively under hydrothermal conditions. The ligands link the metals to a 1D chain via carboxyl groups with μ -(η :η ) and μ -(η :η ) coordination modes. The complexes are assembled into a 3D structure by the 1D chains via hydrogen bonding interactions. The structures have been established by single-crystal X-ray diffraction, and characterized by FT-IR, thermogravimetric analysis (TGA), solid UV-Vis spectroscopy, and solid-state fluorescent spectroscopy. TGA analysis confirmed the thermal stability of the complexes. © 2014 Springer Science+Business Media New York.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84898539372&origin=inward; http://dx.doi.org/10.1007/s10904-014-0026-z; http://link.springer.com/10.1007/s10904-014-0026-z; http://link.springer.com/content/pdf/10.1007/s10904-014-0026-z; http://link.springer.com/content/pdf/10.1007/s10904-014-0026-z.pdf; http://link.springer.com/article/10.1007/s10904-014-0026-z/fulltext.html; https://dx.doi.org/10.1007/s10904-014-0026-z; https://link.springer.com/article/10.1007/s10904-014-0026-z
Springer Science and Business Media LLC
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