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Enhanced Photocatalytic Performance of Zinc Ferrite Nanocomposites for Degrading Methylene Blue: Effect of Nickel Doping Concentration

Journal of Inorganic and Organometallic Polymers and Materials, ISSN: 1574-1451, Vol: 31, Issue: 8, Page: 3496-3504
2021
  • 32
    Citations
  • 0
    Usage
  • 31
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    32
    • Citation Indexes
      32
  • Captures
    31

Article Description

In the present work, undoped and nickel doped zinc ferrite (ZnFeNiO) nano-composites were synthesized using a facile auto-combustion method using glycine as fuel. Effects of Ni dopant concentration and annealing process on structural and morphological properties were investigated by X-ray Diffraction (XRD), Raman spectroscopy, Fourier Transform InfraRed (FTIR) spectroscopy, and Scanning Electron Microscopy/Energy-dispersive X-ray spectroscopy (SEM/EDS). The formation of cubic spinel ferrites is confirmed by XRD analysis while asserting particles with a size range of 55–58 nm. Analysis of Raman spectra showed a transition of normal to inverse spinel-type with the increase in Ni content. Photocatalytic studies of as-synthesized nanoparticles using methylene blue (MB) demonstrated a strong correlation between photocatalytic efficiency and Ni doping. Ni-doped zinc-ferrites exhibited 98% photocatalytic efficiency at an optimum Ni doping concentration of 30%. As-synthesized ferrites have the potential to be used as an efficient, reusable, and magnetically removable photocatalyst system for removing organic pollutants.

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